Nitrogen

Ordered (SBA-15) and disordered (KIL-2) mesoporous silica supports have been synthesized and used for incorporation of titania with different Ti/Si molar ratios (1/2, 1/1, 2/1) via sol–gel impregnation method. Titanium isopropoxide and aqueous titania sol prepared by low-temperature sol–gel processing were used as a source of titania. Characterization by powder X-ray diffraction (XRD), nitrogen sorption measurements, scanning electron microscopy (SEM) and UV–vis–NIR diffuse reflectance spectroscopy (DRS) has been carried out to investigate the chemical framework and morphology of powders. The photocatalytic degradation of isopropanol in the gaseous medium was selected as a probe reaction to test the photoactivity of powders and to verify the potential application of these materials for air remediation. It was found that the titania source, Ti/Si molar ratio and the type of silica support influenced the functional properties of the material, which were evaluated by adsorption capacity and photocatalytic activity in the gas–solid reactor. The adsorption capacity of isopropanol was the highest in the presence of the SBA-15-supported materials. The photoactivity results indicated that the powders which were prepared using SBA-15 as a silica support and a Ti/Si molar ratio of 1/1 were the most active towards isopropanol oxidation monitored in situ by FT-IR spectroscopy.

Ubiquinone-10 (CoQ10), a vitamin-like lipophilic component of the membrane-bound electron transport system, has a wide range of therapeutic, neutraceutical, and cosmeceutical applications. The objective of this study was to optimize nutritional requirements for production of CoQ10 by Paracoccus dinitrificans NRRL B-3785 fermentation. Effect of type and concentration of carbon and nitrogen source on fermentation kinetic parameters were analyzed using logistic and Luedeking-Piret equations. In submerged batch fermentation, yield of CoQ10 was 12.22 mg/L when 40 g/L glycerol was used and specific growth rate (0.056/h) as well as growth associated constant (α=0.680 mg/g) were higher as compared to other concentrations. Ammonium nitrate and proteose peptone at 5 (α=0.677 mg/g; β= 0.0072 mg/g·h) and 20 g/L (α=0.806 mg/g; β=0.0074 mg/g·h), respectively, were optimal for CoQ10 production. CoQ10 formation observed to be both growth and nongrowth associated. In optimized medium CoQ10 formation increased considerably from 1.91 to 14.12 mg/L.

This paper presents the effect of hydric stress on Select sunflower hybrid grown under near-neutral and acid soil conditions. The experiment was conducted in green - house with sunflower plants grown in PVC tubs filled with: near- neutral soil (pH = 6.2 ) (I), acid soil (pH = 5.27) (II) and ferti-lized acid soil ((phosphorus (100 kg/ha), potassium (100 kg/ha)

We have developed a modified physical vapor transport (M-PVT) growth technique for the preparation of SiC single crystals which makes use of an additional gas pipe in order to control the gas phase composition of the conventional physical vapor transport (PVT) configuration. We discuss ...

Two experiments were conducted with growing male rats to determine the effects of 120 ppm of dietary sarsaponin (S) on nitrogen (N) metabolism when urea or protein are added to the diet. Growth, feed efficiency, N digestibility and balance, urinary N and ammonia-N (NH3-N), and cecal urease and NH3-N were measured. Growth and feed utilization were unaffected by dietary S. Adding urea or protein to the diet increased apparent N digestibility and increased urinary-N excretion. Urea did not affect N balance, whereas growth, feed utilization and N balance were maximized with 22% compared with either 16 or 28% dietary protein. Urinary NH3-N excretion was decreased by S when urea was added to the diet but was not affected when fed with increasing dietary protein. Cecal urease was decreased by S when urea was added or when the protein level was increased in the diet; effects on cecal NH3-N varied between the two experiments. Plasma urea-N was decreased by S. It is concluded that S has minor...

Highly selective synthesis of diphenylmethane (DPM) was carried out by Friedal–Crafts benzylation of benzene using benzyl chloride (BC) as alkylating agent in the presence of a flow of nitrogen under liquid phase reaction conditions over novel mesoporous SO42−/Al-MCM-41 catalysts with different Si/Al ratios. For these reactions, the influences of various reaction parameters, such as different catalysts, reaction temperature, time, mmol

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Cellulose nanofibers with a size range of 5–100 nm have the potential to be a low cost renewable material that has application in a range of products. However, current chemical methods to produce crystalline nanofibers suffer from low yields and high chemical costs, while mechanical methods require high energy costs. Methods to lower the energy costs of the mechanical methods have not been well documented in the literature. A bleached softwood kraft pulp was processed using a mechanical dispersion mill and a homogenizer to produce cellulose nanofibers. Two different commercial enzymes were used to pretreat the wood fibers before the mechanical treatments. The resulting nanofibers were characterized by light microscopy, atomic force microscopy, and inverse gas chromatography. Results indicate that the dispersion mill does not affect the overall pulp fiber fibrillation, but does help prepare the sample for the homogenizer. Most fibrillation occurs after three passes through the homogenizer. The enzyme pretreatment has little effect on the size of the fibers, but does allow for higher solids to pass through the homogenizer without clogging. The dispersion component of surface energy of the resulting nanofibrils is impacted by the type of enzyme used. The measurement of acid–base properties proved to be challenging using current IGC experimental protocols.

We present experimental laboratory evidence and field observations of an autocatalyzed, programmed cell death (PCD) pathway in the nitrogen-fixing cyanobacteriumTrichodesmium spp., which forms massive blooms in the subtropical and tropical oceans. The PCD pathway was induced in response to phosphorus and iron starvation as well as high irradiance and oxidative stress. Transmission electron microscopy revealed morpho- logical degradation of internal

Nitrogen (N) and phosphorus (P) and N: P ratio in terrestrial plants and the patterns at a large geographical scale are an important issue in ecological stoichiometry. In particular, it is essential to know that for a single species, how the N: P stoichiometry varies with climatic ...

The creep properties of a nuclear-grade type 316 (L) stainless steel (SS) alloyed with nitrogen (316L (N) SS) and its weld metal were studied at 873 and 923 K in the range of applied stresses from 100 to 335 MPa. The results were compared with those obtained on ...

O objetivo deste trabalho foi avaliar as produções vegetal e animal e a resposta econômica de uma pastagem natural submetida à adubação de correção e doses de nitrogênio durante a estação de crescimento 1998/99. O experimento foi conduzido em área da Estação Experimental Agronômica da Universidade Federal do Rio Grande do Sul (EEA - UFRGS). Em 1996 foram aplicados 3000kg ha-1 de calcário e adubação correspondente a 500kg ha-1 da fórmula 5-20-20. Na análise econômica, considerou-se um terço destas quantidades como referente à utilização na estação de crescimento 1998/99. Os tratamentos foram doses de nitrogênio (N) na forma de uréia (zero, 100 e 200kg ha-1 de N), em um delineamento de blocos ao acaso com duas repetições de área por tratamento. Os animais experimentais foram novilhas de corte com um ano de idade e peso médio inicial de 160kg. A massa de forragem, a taxa de acúmulo diário de matéria seca, a produção total de matéria seca verde e a eficiência de transformação do N em pr...

The environmental effects of the three strawberry (Fragaria ×ananassa) cold-climate production systems were compared: the traditional method of conventional matted row (CMR) and the two more recently developed practices of advanced matted row (AMR) and cold-climate plasticulture (CCP). Side-by-side field plots were instrumented with automated flow meters and samplers to measure and collect runoff, which was filtered and analyzed to determine soil, pesticide, and nitrogen losses. Although annual mean runoff volumes were similar for all three production systems, the soil losses from CMR plots were two to three times greater than the CCP plots throughout the study and two to three times greater than the AMR plots only in the first year of the 3-year study. In general, decreases in erosion and runoff volumes were observed in plots that were disturbed less by machine operations and had less foot traffic as a result of decreased need for hand weeding and in the plots that used straw mulch...

Under field conditions in Osijek during two years were set field trials. The aim was confirm an influences of irrigation rate, nitrogen (N) fertilization and soybean varieties on grain yield and some yield components. The irrigation treatments were: control (A1) ; soil moisture content from 60% to 100% retention water capacity (RWC, A2) and soil moisture content from 80% to 100% RWC (A3). Rate of N was sub sub-factor: 0 (B1) ; 100 (B2) and 200 kg N ha-1 (B3), were applied. Una (C1) and Anica (C2) soybean varieties was sub-sub factor (C). Mean soybean grain yields were 3082 kg ha-1 and 3538 kg ha-1 in years 2006 and 2007, respectively. Irrigation resulted by high statistically difference in soybean grain yield in both investigated years and between all treatments. Variety Una yielded (3179 kg ha-1) statistically very higher in 2006. Interactions AB, AC and BC on pod number plant-1 were significant in one year, only. Thousand grain weight (g) resulted with high significant higher valu...

Switchgrass ( L.) has been promoted as a potential feedstock for cellulosic biofuel in the United States. Switchgrass is known to respond to N fertilizer, but optimal rates remain unclear. Given the potential nonlinear response of nitrous oxide (NO) emissions to N inputs, N additions to switchgrass above optimal levels could have large impacts on the greenhouse gas balance of switchgrass-based biofuel. Additionally, N additions are likely to have large impacts on switchgrass production costs. Yield, N removal, and net returns were measured in switchgrass receiving 0 to 200 kg N ha in Manhattan, KS, from 2012 to 2014. Emissions of NO were measured in the 0- to 150-kg N ha treatments. Total emissions of NO increased from 0.2 to 3.0 kg NO-N ha as N inputs increased from 0 to 150 kg N ha. The 3-yr averages of fertilizer-induced emission factors were 0.7, 2.1, and 2.6% at 50, 100, and 150 kg N ha, respectively. Removal of N at harvest increased linearly with increasing N rate. Switchgras...

Air quality indices currently in use have been criticized because they do not capture additive effects of multiple pollutants, or reflect the apparent no-threshold concentration-response relationship between air pollution and health. We propose a new air quality health index (AQHI), constructed as the sum of excess mortality risk associated with individual pollutants from a time-series analysis of air pollution and