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CO. This does not mean, however, that all
such assignments are suspect. There are
certainly examples, including Pt(ll1) and
various Cu surfaces, where CO sites deduced in this way have been confirmed by
direct structural methods. Nevertheless,
frequency boundaries between bridgeand hollow-sites in particular, but also between bridge- and top-sites, are obviously
less well-defined than had been thought
and deductions from vibrational data alone
must now be regarded as no more than
tentative.
During the round table, the quality ofthe
presentations and the stimulating discussions were emphasized. The organisation of a fourth workshop was decided, to
be held in France during 1996.
D. DUPREZ
Solid Oxide Fuel Ceils
The 3rd France-Maghreb Catalysis
Workshop was held in Rabat from 9th to
12th May 1994 under the auspices of the
Algerian, French (Catalysis Division), Moroccan and Tunisian Chemical Societies.
The opening session was chaired by M.
Knidiri, Morrocan Minister of Education.
The workshop, on the central theme of
catalysis applied to environmental protection, drew 126 participants, of whom 20
were French and 25 were PhD students
from the Maghreb studying in French laboratories. Four lectures were given by
French specialists, three on characterisation
techniques
(UV-Visible-PIR,
thermal methods and chemisorption), thus
completing the lectures on characterisation methods given at the two previous workshops, and one on polyfunctional catalysis for treating car exhausts.
About
100
communications
were
presented, either orally (36) or as posters.
The workshop ended with a visit to the
Maroc-Phosphore factory at El Jadida.
While all hydrogen-compatible fuel
cells with acidic, alkaline or polymer electrolytes need special reformers to work on
natural gas, Solid Oxide Fuel Ceils
(“SOFC”) can convert gaseous hydrocarbons directly or with internal reforming into
electricity with high efficiency wlth low
emissions and without moving pans. The
electrolyte is a thin ceramic membrane
composed of yttria-stabiiised zirconia.
When heated to around %Kt%, ionised
oxygen from ordinary air passes from the
cathode through the ceramic electrolyte to
the anode where fuel gases are oxidised.
Hydrocarbons are reformed to hydrogen
and carbon monoxide within the hot system envelope. Natural or coal gas, liquid
gas or vaporised liquid fuels can thus be
converted to direct current electric power.
Also, useful excess heat is available at high
temperature levels. Thus, solid oxide fuel
cells are likely to play a dominant role in
co-generation in the near future.
in hydrogen-compatible fuel cell concepts, carbon poisons the electrolyte.
Carbon oxides must be carefully removed
from the feed gas to avoid power loss and
system failure. However, the SOFC offers
a perfect compatibility with hydrocarbon
fuels. As a consequence, the market
potential of the SOFC is impressive for
today’s energy environment. Because of
these advantages, SOFC technology is
applied catalysis A: General
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Frsflco-Maghreb Catalysis Workshop
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1 September 1964
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under rapid development in Europe, the
US, Japan and Australia.
In recent years, the technology has matured rapidly. The first products will appear
on the market soon. SOFC technology is a
candidate for applications such as: dispersed power generation and co-generation with natural gas; on-board power
generation for trucks, buses, boats, trains
or planes with diesel fuel; air-cooled power
plants with natural or coal gas; electric
power sources for hybrid road vehicles
with methanol, gasoline or diesel fuel; and
space and military applications with hydrogen and oxygen.
Projected costs of SOFC systems compare favourably with those of conventional
conversion technologies. Consequently,
the SOFC is expecting a bright future. Conservative market assessments forecast
world-wide sales exceeding one billion US
dollars per year soon after the year 2ooo.
Because of these promising aspects
the European Solid Oxide Fuel Cell Forum
(forum = conference + exhibition + commercial interaction) has been initiated as a
biennial event, The first one will be held at
Lucerne in Switzerland from 3rd to 7th October, 1974. The aim of the European
SOFC Forum is to relate the attractive
SOFC technology to the market.
Further information may be obtained
from the address given in the Calendar.
Mlcroscopy
and Catalysis
A joint one-day meeting of the Royal
Microscopical Society and the Surface Reactivity and Catalysis Group of the Royal
Society of Chemistry will be held on Thurs-
applied catalysis A: General
day 27th October at the Royal Institqtion,
21 Albermarle Street, London. The subject
of the meeting will be Microscopy and
Catalysis. A knowledge of the physical
form and local chemical composition of an
efficient heterogeneous catalyst is needed
at all stages of its operation: before, during
and after reaction. Furthermore, this information is becoming necessary at increasingly high spatial resolutions and for ever
more complex systems. The different branches of microscopy therefore have an important contribution to make to catalysis
research, and this field poses particular
challenges to the microscopist because of
the dependence of the critical chemical
processes on localised surface behaviour.
The aim of this one-day meeting is to
bring together individuals and groups
whose work relates to microscopy and
catalysis. The meeting will highlight the
contributions which electron and scanned
probe microscopies are making to research in heterogeneous catalysis. There
will be contributions from those who are
specialists in either chemistry or materials
science but whose interests bridge both
areas. The organisers of the meeting,
which will include an invited presentation
from Professor Sir John Meurig Thomas
and contributions from meeting registrants, are Prof. Richard Joyner (Leverhulme Centre for Innovative Catalysis,
University of Liverpool, UK) and Dr. Erica
Bithell (Department of Materials, University
of Oxford. For further information, contact
the Administrator, the Royal Microscopical
Society, at the address given in the Calendar of Forthcoming Events.
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1 September 1994